Vol. 32, issue 05, article # 9

Belan B. D., Savkin D. E. The role of air humidity in variations in the surface ozone concentration. // Optika Atmosfery i Okeana. 2019. V. 32. No. 05. P. 395–398. DOI: 10.15372/AOO20190509 [in Russian].
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Abstract:

The dependence of variations in the surface ozone concentration on the absolute air humidity is studied based on measurements at the TOR station in 1994–2017. The analysis performed revealed a neutral dependence at positive temperatures and unexpectedly strong and alternating sign variability at negative temperatures. The absolute air humidity negatively affects the ozone formation in the surface air layer, decreasing the ozone concentration at temperatures of 0…-30 °C. At very low temperatures (lower -30 °C) the effect becomes positive, i.e., the ozone concentration on increases with the absolute air humidity.

Keywords:

atmosphere, gas, humidity, air, ozone

References:

  1. Lunin V.V., Popovich M.P., Tkachenko S.N. Fizicheskaya himiya ozona. M.: MGU, 1998. 480 p.
  2. Belan B.D. Ozon v troposfere. Tomsk: Izd-vo IOA SO RAN, 2010. 488 p.
  3. Monks P.S., Archibald A.T., Colette A., Cooper O., Coyle M., Derwent R., Fowler D., Granier C., Law K.S., Mills G.E., Stevenson D.S., Tarasova O., Thouret V., von Schneidemesser E., Sommariva R., Wild O., Williams M.L. Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer // Atmos. Chem. Phys. 2015. V. 15, N 15. P. 8889–8973.
  4. Yadav R., Sahu L.K., Beig G., Jaaffrey S.N.A. Role of long-range transport and local meteorology in seasonal variation of surface ozone and its precursors at an urban site in India // Atmos. Res. 2016. V. 176–177. P. 96–107.
  5. Gunthe S.S., Beig G., Sahu L.K. Study of relationship between daily maxima in ozone and temperature in an urban site in India // Curr. Sci. 2016. V. 110, N 10. P. 1994–1999.
  6. Munir S., Habeebullah T.M., Ropkins K., Seroji A.R. Modelling ozone-temperature slope under atypically high temperature in arid climatic conditions of Makkah, Saudi Arabia // Aerosol Air Quality Res. 2015. V. 15, N 4. P. 1281–1290.
  7. Jasaitis D., Vasiliauskien V., Chadyšien R., Peciuliene M. Surface ozone concentration and its relationship with UV radiation, meteorological parameters and Radon on the Eastern Coast of the Baltic Sea // Atmos. 2016. V. 7, N 27. DOI: 10.3390/atmos7020027.
  8. Pavón-Domínguez P., Jiménez-Hornero F.J., Gutiérrez de Ravé E. Proposal for estimating ground-level ozone concentrations at urban areas based on multivariate statistical methods // Atmos. Environ. 2014. V. 90. P. 59–70.
  9. Toh Y.Y., Lim S.F., von Glasow R. The influence of meteorological factors and biomass burning on surface ozone concentrations at Tanah Rata, Malaysia // Atmos. Environ. 2013. V. 70. P. 435–446.
  10. Tereb N.V., Milekhin L.I., Milekhin V.L., Gnilomedov V.D., Nechaev D.R., Kulizhnikova L.K., SHirotov V.V. Soderzhanie prizemnogo ozona v usloviyah anomal'nogo leta 2010 year po izmereniyam v g. Obninske // Meteorol. i gidrol. 2013. N 5. P. 14–25.
  11. Tawfik A.B., Steiner A.L. A proposed physical mechanism for ozone-meteorology correlations using land-atmosphere coupling regimes // Atmos. Environ. 2013. V. 72. P. 50–59.
  12. Crutzen P.J., Zimmermann P.H. The changing photochemistry of the troposphere // Tellus B. 1991. V. 43, N 4. P. 136–151.
  13. Levy H.II. Normal atmosphere: Large radical and formaldehyde concentrations predicted // Science. 1971. V. 173, N 3992. P. 141–143.
  14. Davydov D.K., Belan B.D., Antohin P.N., Antohina O.Yu., Antonovich V.V., Arshinova V.G., Arshinov M.Yu., Ahlestin A.Yu., Belan S.B., Dudorova N.V., Ivlev G.A., Kozlov A.V., Pestunov D.A., Rasskazchikova T.M., Savkin D.Е., Simonenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fazliev A.Z., Fofonov A.V. Monitoring atmosfernyh parametrov: 25 let TOR-stantsii IOA SO RAN // Optika atmosf. i okeana. 2018. V. 31, N 10. P. 845–853; Davydov D.K., Belan B.D., Аntokhin P.N., Antokhina O.Yu., Antonovich V.V., Arshinova V.G., Arshinov M.Yu., Akhlyostin A.Yu., Belan S.B., Dudorova N.V., Ivlev G.A., Kozlov A.V., Pestunov D.A., Rasskazchikova T.M., Savkin D.E., Simonenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fazliev A.Z., Fofonov A.V. Monitoring of atmospheric parameters: 25 years of the Tropospheric Ozone Research Station of the Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences // Atmos. Ocean. Opt. 2019. V. 32, N 2. P. 180–192.
  15. Belan B.D., Savkin D.Е., Tolmachev G.N. Zavisimost' obrazovaniya ozona v prizemnom sloe ot temperatury vozduha // Optika atmosf. i okeana. 2017. V. 30, N 11. P. 971–979; Belan B.D., Savkin D.E., Tolmachev G.N. Generation of ozone in the surface air layer versus air temperature // Atmos. Ocean. Opt. 2018. V. 31, N 2. P. 187–196.