Vol. 5, issue 10, article # 15

Zuev V. V., Petrova A. I. On the problem of the deterministic connection between the distribution of molecules over quantum states and velocities. // Atmospheric and oceanic optics. 1992. V. 5. No. 10. P. 714-716.    PDF
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Abstract:

Considering the process of CO self–broadening as an example it is shown that the strong binary collisions of molecules determine the most probable molecular velocity vj associated with every quantum number J via the molecular distribution over the quantum states.