Vol. 5, issue 09, article # 6

Starikov V. I., Mikhailenko S. N. Use of generating functions in calculations of rovibrational energies of the CH2 radical. // Atmospheric and oceanic optics. 1992. V. 5. No. 09. P. 615-621. PDF
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This paper presents a discussion of qualitative studies of the rotational energy of nonrigid molecules of H2X type on the quantum number K characterizing a projection of the angular momentum operator onto the molecular linearization axis Z. The frequencies of rotational and rovibrational transitions are processed for the CH2 molecule using the generating functions for an effective rotational Hamiltonian. Rotational energies of the vibrational states (000) and (010) are reconstructed.