Vol. 4, issue 11, article # 10
Gal'tsev A. P., Kuznetsov M. N. On the role of detailed balance in the line mixing treatment. // Atmospheric and oceanic optics. 1991. V. 4. No. 11. P. 821-824.
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Abstract:
A theoretical study of spectral line mixing is carried out on the basis of the general expression for detailed balance, providing thermodynamic equilibrium in a gas phase. Results of calculations are compared with those obtained using the model of strong collisions and the model of weak line coupling. It is shown that the absorption in the wings of rovibrational bands calculated for these cases may differ from measured values by an order of magnitude.
