Vol. 3, issue 06, article # 3
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Abstract:
The original set (up to second order inclusively) of derivatives of the dipole moment of H2O was determined by solving the inverse electrooptical problem based on the integral intensities, measured experimentally at the normal temperatures, of the vibrational transitions whose wave function incorporates vibrational resonances and anharmonicity. The obtained set was used to extrapolate (to T~2500ºK) the integral intensities of the band formed by transitions with high quantum numbers (V≤4). The centers and intensities of the vibrational-rotational lines of H2O were calculated and a data base was constructed for the parameters of the spectral lines of H2O for the temperature range 300-2500ºK.
References:
1. O.K. Voitsekhovskaya. N.N. Trifonova, and A. V. Rozina, Information System for High- Resolution Spectroscopy [in Russian], Nauka, Novosibirsk (1988), 150 pp.
2. M.R. Aliev and J.C.G. Watson, J. Mol. Spectr. 62, No. 1, 29–52 (1976).
3. A.D. Bukov, Yu.S. Makushkin, and O.N. Ulenikov, J. Mol. Spectr. 99, No. 20, 221–227 (1983).
4. D. Papousek and M.R. Aliev, Molecular Vibrational-Rotational Spectra, Academia, Pragua (1982).
5. G. Amat, H.H. Nielsen, and G. Tarrago, Rotation- Vibration Spectra of Polyatomic Molecules, M. Dekker, New York (1971), 519 pp.
6. Yu.S. Makushkin and V.G. Tyuterev, Perturbation and Effective-Hamiltonians Methods in Molecular Spectroscory [in Russian), Nauka, Novosibirsk (1984).
7. D. Berckmans, H.P. Figeys, and P. Geerlings, J. Molec. Struct. (Theochem) 148, 81–100 (1986).
8. C. Secroun, A. Barbe, and P. Jouve, J. Mol. Spectr. 45, No. 1, 1–9 (1973)
9. S.J. Yao and J. Overend, Spectrochim Acta, 32A, No. 5, 1059–1066 (1976).
10. Y. Yamaoka and K. Machida, J. Mol. Spectr. 190, No. 2, 234–244 (1983).
11. J.M. Flaud and C. Cauay-Peyret, Etude Vibrorotationnelle de la Molecule H2O, Author's Abstract of Doctorate of Sci. Phys. (1975).
12. D.L. Albritton, A.L. Schmeltekopf, and R.N. Zare, Molecular Spectroscopy. Modern Research, Acad. Press. , New York 11, Ch. 1, 1–67 (1976);
13. J.M. Flaud and C. Camy-Peyret, Molecular Spectroscopy, Modern Research. Acad. Press., New York 111 (1985).
14. A. Chedin, M. Hussen, N.A. Scott, Cohen-Hallaleh, and A. Berrior, The GEISA Data Bank: 1984 Version, Laboratoric de Meteorol. Dynamique du C.N.R.S. (1985–1986).
15. O.K. Voitsekhovskaya, Yu.S. Makushkin, N.N. Trifonova, and V.N. Cherepanov, "Program for calculating vibrational-rotational, line centers and intensities for asymmetric-top molecules", COSFAP, No. 004348 (1980).
16. O.K. Voitsekhovskaya. N.N. Trifonova, and N.V. Kuzmina, Opt. Atmos. 3, No. 5, 485–493 (1990).
17. S.P. Gavva, Candidates Dissertation in Physical Mathematical Sciences, Saratov Polytechnical Institute, Saratov (1984).
18. W.C. Ermler and B.J. Krohn, J. Chem. Phys. 67, 1360–1370 (1977).
19. A.S. Pine et al., J. Chem. Phys. 12, No. 1, 413–465 (1965).
20. C.Y. Maclay, J. Chem. Phys. 43, No. 1. 185–191 (1965).
21. Ben Aryeh, J. Quant. Spectrosc. Rad. Transf. 7, 211–224 (1967).
22. C. Camy-Peyret et al., J. Mol. Spectr. 110, 208–228 (1985).
