Том 31, номер 04, статья № 3
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Аннотация:
Полоса ν2 исследована на основе метода комбинационных разностей с использованием FTIR-спектра высокого разрешения молекулы SO2 в диапазоне 400–700 см-1. Проинтерпретировано более 4500 линий с максимальными значениями квантовых чисел J и Kа, равными 96 и 25 соответственно. На этой основе определено 1294 энергетических колебательно-вращательных уровней состояния (010). В результате решения обратной задачи с использованием этих уровней получено 32 параметра эффективного гамильтониана, которые позволяют воспроизводить исходные экспериментальные данные с точностью drms = 1,9 × 10-4 см-1.
Ключевые слова:
диоксид серы, спектр высокого разрешения, фундаментальная полоса
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