Vol. 32, issue 08, article # 8

Arshinova V.G., Belan B.D., Lapchenko V.A., Lаpchenkо E.V., Rasskazchikova T.M., Savkin D.E., Sklyadneva T.K., Tolmachev G.N., Fofonov A.V. Variations in the ozone concentration in precipitation. // Optika Atmosfery i Okeana. 2019. V. 32. No. 08. P. 657–664 [in Russian].
Copy the reference to clipboard
Abstract:

Changes in the ozone concentration during precipitation is studied on the basis of surface ozone monitoring data in Tomsk and on the Karadag. It is revealed that these changes can be both positive and negative. The maximal ozone content jumps are observed during frontal precipitations. During air mass precipitation, the sign and magnitude of the changes are defined by the daily ozone cycle. The analysis showed coincidence between an increase in the ozone concentration during precipitation with its increase in the daily cycle in 59% of cases in Tomsk and in 63% of cases on the Karadag. The coincidence of a decrease in the O3 concentration during precipitation with the ozone decrease wave in the daily cycle is observed even more often, in 85% of cases in Tomsk and in 79% of cases on the Karadag. Based on the aircraft sounding data, ozone sink from the boundary air layer is observed in some cases when the temperature stratification is changing to neutral in precipitation.

Keywords:

atmosphere, gas, air, washout, ozone, precipitation, impurity, removal

Figures:
References:

  1. Monks P.S., Archibald A.T., Colette A., Cooper O., Coyle M., Derwent R., Fowler D., Granier C., Law K.S., Mills G.E., Stevenson D.S., Tarasova O., Thouret V., von Schneidemesser E., Sommariva R., Wild O., Williams M.L. Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer // Atmos. Chem. Phys. 2015. V. 15, N 15. P. 8889–8973.
  2. Hajklin Dzh. Vyvedenie gazov iz atmosfery aerozol'nymi chastitsami // Geterogennaya himiya atmosfery. L.: Gidrometeoizdat, 1986. P. 171–182.
  3. Nair P.R., David L.M., Aryasree A., George K.S. Distribution of ozone in the marine boundary layer of Arabian Sea prior to monsoon: Prevailing airmass and effect of aerosols // Atmos Environ. 2013. V. 74. P. 18–28.
  4. Gopal K.R., Lingaswamy A.P., Arafath S.M., Bala­krishnaiah G.S., Kumari P., Devi K.U., Reddy N.S.K., Reddy K.R.O., Reddy R.R., Azeem P.A., Lal S. Sea­sonal heterogeneity in ozone and its precursors (NOx) by in-situ and model observations on semi-arid station in Anantapur (A.P), South India // Atmos. Environ. 2014. V. 84. P. 294–306.
  5. Bela M.M., Longo K.M., Freitas S.R., Moreira D.S., Beck V., Wofsy S.C., Gerbig C., Wiedemann K., An­dreae M.O., Artaxo P. Ozone production and trans­port over the Amazon Basin during the dry-to-wet and wet-to-dry transition seasons // Atmos. Chem. Phys. 2015. V. 15, N 2. P. 757–782.
  6. Gunthe S.S., Beig G., Sahu L.K. Study of relationship between daily maxima in ozone and temperature in an urban site in India // Curr. Sci. 2016. V. 110, N 10. P. 1994–1999.
  7. Liu P.-W.G., Tsai J.-H., Lai H.C., Tsai D.-M., Li L.-W. Establishing multiple regression models for ozone sensitivity analysis to temperature variation in Taiwan // Atmos. Environ. 2013. V. 79. P. 225–235.
  8. Balashov N.V., Thompson A.M., Piketh S.J., Langerman K.E. Surface ozone variability and trends over the South African Highveld from 1990 to 2007 // J. Geophys. Res.: Atmos. 2014. V. 119, N 7. P. 4323–4342.
  9. Toh Y.Y., Lim S.F., von Glasow R. The influence of meteorological factors and biomass burning on surface ozone concentrations at Tanah Rata, Malaysia // Atmos. Environ. 2013. V. 70. P. 435–446.
  10. Wang Z., Sassen K. Ozone distruction in continental status clouds: An aircraft case study // J. Appl. Meteorol. 2000. V. 39, N 6. P. 875–886.
  11. Arshinov M.YU., Belan B.D., Tolmachev G.N., Fofonov A.V. Masshtab destruktsii troposfernogo ozona v oblakah // Optika atmosf. i okeana. 2010. V. 23, N 1. PС. 43–46; Arshinov M.Yu., Belan B.D., Tolmachev G.N., Fofonov A.V. The scale of tropospheric ozone destruction in clouds // Atmos. Ocean. Opt. 2010. V. 23, N 2. P. 106–110.
  12. Jacob D. Heterogeneous chemistry and tropospheric ozone // Atmos. Environ. 2000. V. 34, N 12–14. P. 2131–2159.
  13. Reichardt J., Ansmann A., Serwazi M., Weitkamp C., Michaelis W. Unexpectedly low ozone concentration in midlatitude tropospheric ice clouds: A case study // Geophys. Res. Lett. 1996. V. 23, N 15. P. 1929–1932.
  14. Tawfik A.B., Steiner A.L. A proposed physical me­chanism for ozone-meteorology correlations using land-atmosphere coupling regimes // Atmos. Environ. 2013. V. 72. P. 50–59.
  15. Melkonyan A., Wagner P. Ozone and its projection in regard to climate change // Atmos. Environ. 2013. V. 67. P. 287–295.
  16. Davydov D.K., Belan B.D., Antohin P.N., Antohina O.Yu., Antonovich V.V., Arshinova V.G., Arshinov M.Yu., Ahlestin A.Yu., Belan S.B., Dudorova N.V., Ivlev G.A., Kozlov A.V., Pestunov D.A., Rasskazchikova T.M., Savkin D.E., Simonenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fazliev A.Z., Fofonov A.V. Monitoring atmosfernyh parametrov: 25 let TOR-stantsii IOA SO RAN // Optika atmosf. i okeana. 2018. V. 31, N 10. P. 845–853; Davydov D.K., Belan B.D., Аntokhin P.N., Antokhina O.Yu., Antonovich V.V., Arshinova V.G., Arshinov M.Yu., Akhlyostin A.Yu., Belan S.B., Dudorova N.V., Ivlev G.A., Kozlov A.V., Pestunov D.A., Rasskazchikova T.M., Savkin D.E., Simonenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fazliev A.Z., Fo­fonov A.V. Monitoring of atmospheric parameters: 25 years of the Tropospheric Ozone Research Station of the Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences // Atmos. Ocean. Opt. 2019. V. 32, N 2. P. 180–192.
  17. Belan B.D. Ozon v troposfere. Tomsk: IOA SO RAN, 2010. 488 p.
  18. Lunin V.V., Popovich M.P., Tkachenko S.N. Fizicheskaya himiya ozona. M.: MGU, 1998. 480 p.
  19. Kogan V.B., Fridman V.N., Kofarov V.V. Spravochnik po rastvorimosti, 1961. V. 1, book 1. 380 p.
  20. Arshinova V.G., Belan B.D., Rasskazchikova T.M., Rogov A.N., Tolmachev G.N. Izmenenie kontsentratsii ozona v prizemnom sloe vozduha pri prohozhdenii atmosfernyh frontov // Optika atmosf. i okeana. 1995. V. 8, N 4. P. 625–631.
  21. Blyum O.B., Budak I.V., Dyachuk V.A., Sosonkin M.G., Shavrina A.V. Prizemnij ozon u Kievi, umovi jogo utvorennya i stoku // Nauk. Pratsi UkrNDGMI. 2002. Iss. 250. P. 68–76.
  22. Ojha N., Naja M., Singh K.P., Sarangi T., Kumar R., Lal S., Lawrence M.G., Butler T.M., Chan­dola H.C. Variabilities in ozone at a semi-urban site in the Indo-Gangetic Plain region: Association with the meteorology and regional processes // J. Geophys. Res. 2012. V. 117, N D20301. DOI: 10.1029/2012JD017716.
  23. Oyola O.I., Schneider A., Campbell J., Joseph E. Meteorological influences on tropospheric ozone over suburban Washington, DC // Aerosol Air Qual. Res. 2018. V. 18, N 5. P. 1168–1182.
  24. Wang H., Lyu X., Guo H., Wang Y., Zou S., Ling Z., Wang X., Jiang F., Zeren Y., Pan W., Huang X., Shen J. Ozone pollution around a coastal region of South China Sea: Interaction between marine and continental air // Atmos. Chem. Phys. 2018. V. 18, N 6. P. 4277–4295.
  25. Antohina O.YU., Antohin P.N., Arshinova V.G., Arshinov M.Yu., Belan B.D., Belan S.B., Davydov D.K., Dudorova N.V., Ivlev G.A., Kozlov A.V., Rasskazchikova T.M., Savkin D.E., Simonenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fofonov A.V. Issledovanie sostava vozduha v razlichnyh vozdushnyh massah // Optika atmosf. i okeana. 2018. V. 31, N 9. P. 752–759; Antokhina O.Yu., Аntokhin P.N., Arshinova V.G., Arshinov M.Yu., Belan B.D., Be­lan S.B., Davydov D.K., Dudorova N.V., Ivlev G.A., Kozlov A.V., Rasskazchikova T.M., Savkin D.E., Si­monenkov D.V., Sklyadneva T.K., Tolmachev G.N., Fofonov A.V. Study of the composition of air masses of different types // Atmos. Ocean. Opt. 2019. V. 32, N 1. P. 72–79.
  26. Khromov S.P. Osnovy sinopticheskoj meteorologii. L.: Gidrometeoizdat, 1948. 700 p.
  27. Belan B.D., Zade G.O., Plotnikov A.P., Rasskazchikova T.M., Sklyadneva T.K. Izmenenie sostava vozduha pri prohozhdenii atmosfernyh frontov // Meteorol. i gidrol. 1999. N 11. P. 34–39.
  28. Belan B.D., Sklyadneva T.K. Sutochnyj hod kontsentratsii prizemnogo ozona v rajone g. Tomska // Meteorol. i gidrol. 2001. N 5. P. 50–60.
  29. Lapchenko V.A., Zvyagintsev A.M. Malye gazovye sostavlyayushchie atmosfery v Karadagskom prirodnom zapovednike v Krymu // Optika atmosf. i okeana. 2015. V. 28, N 2. P. 178–181; Lapchenko V.A., Zvyagintsev A.M. Trace atmospheric gases in the Karadag nature reserve in Crimea // Atmos. Ocean. Opt. 2015. V. 28, N 4. P. 308–311.
  30. Shalygina I.Yu., Kuznetsova I.N., Zvyagintsev A.M., Lapchenko V.A. Prizemnyj ozon na poberezh'yah Balkanskogo poluostrova i Kryma // Optika atmosf. i okeana. 2017. V. 30, N 6. P. 515–523.
  31. Pregger T., Friedrich R. Effective pollutant emission heights for atmospheric transport modeling based on real-world information // Environ. Pollut. 2009. V. 157, N 2. P. 552–560.
  32. Pozzer A., Jockel P., Van Ardenne J. The influence of the vertical distribution of emissions on tropospheric chemistry // Atmos. Chem. Phys. 2009. V. 9, N 24. P. 9417–9432.
  33. Antohin P.N., Arshinov M.Yu., Belan B.D., Belan S.B., Davydov D.K., Kozlov A.V., Krasnov O.A., Pestunov D.A., Praslova O.V., Fofonov A.V., Inoue G., Machida T., Maksutov Sh.Sh., Shimoyama Ko., Sutoh H. Primenenie samoleta An-2 dlya issledovaniya sostava vozduha v pogranichnom sloe atmosfery // Optika atmosf. i okeana. 2012. V. 25, N 8. P. 714–720.
  34. Antohin P.N., Arshinova V.G., Arshinov M.Yu., Belan B.D., Belan S.B., Davydov D.K., Kozlov A.V., Krasnov O.A., Praslova O.V., Rasskazchikova T.M., Savkin D.E., Tolmachev G.N., Fofonov A.V. Sutochnaya dinamika vertikal'nogo raspredeleniya ozona v pogranichnom sloe atmosfery v rajone Tomska // Optika atmosf. i okeana. 2013. V. 26, N 8. P. 665–672.
  35. Kalabokas P.D., Thouret V., Cammas J.-P., Volz-Thomas A., Boulanger D., Reparis C.C. The geographical distribution of meteorological parameters associated with high and low summer ozone levels in the lower troposphere and the boundary layer over the eastern Mediterranean (Cairo case) // Tellus B. 2015. V. 67. P. 27853. [Electronic resource]. URL: http://dx.doi.org/10.3402/tellusb.v67.27853.
  36. Borovikov A.M., Gajvoronskij I.I., Zak E.G., Kostarev V.V., Mazin I.P., Minervin V.E., Hrgian A.X., Shmeter S.M. Fizika oblakov. L.: Gidrometeoizdat, 1961. 459 p.
  37. Wonaschuetz A., Sorooshian A., Ervens B., Chuang P.Y., Feingold G., Murphy S.M., de Gouw J., Warneke C., Jonsson H.H. Aerosol and gas re-distribution by shallow cumulus clouds: An investigation using airborne measurements // J. Geophys. Res. 2012. V. 117, N D17202. DOI: 10.1029/2012JD018089.
  38. Croft B., Lohmann U., Martin R.V., Stier P., Wurzler S., Feichter J., Hoose C., Heikkila U., van Don­kelaar A., Ferrachat S. Influences of in-cloud aerosol scavenging parameterizations on aerosol concentrations and wet deposition in ECHAM5-HAM // Atmos. Chem. Phys. 2010. V. 10, N 4. P. 1511–1543.
  39. Elperin T., Fominykh A., Krasovitov B., Vikhansky V. Effect of rain scavenging on altitudinal distribution of soluble gaseous pollutants in the atmosphere // Atmos. Environ. 2011. V. 45, N 14. P. 2427–2433.
  40. Duhanyan N., Roustan Y. Below-cloud scavenging by rain of atmospheric gases and particulates // Atmos. Environ. 2011. V. 45, N 39. P. 7201–7217.
  41. Paramonov M., Gronholm T., Virkkula A. Below-cloud scavenging of aerosol particles by snow at an urban site in Finland // Boreal Environ. Res. 2011. V. 16, N 4. P. 304–320.
  42. Crawford J., Olson J., Davis D., Chen G., Barrick J., Shetter R., Lefer B., Jordan C., Anderson B., Clarke A., Sachse G., Blake D., Singh H., Sandolm S., Tan D., Kondo Y., Avery M., Flocke F., Eisele F., Mauldin L., Zondlo M., Brune W., Harder H., Martinez M., Talbot R., Bandy A., Thornton D. Clouds and trace gas distributions during TRACE-P // J. Geophys. Res. 2003. V. 108, N D21. P. 8818. DOI: 10.1029/2002JD003177.
  43. Arshinov M.Yu., Belan B.D., Davydov D.K., Ivlev G.A., Kozlov A.S., Kozlov V.S., Panchenko M.V., Penner I.E., Pestunov D.A., Safatov A.S., Simonenkov D.V., Tolmachev G.N., Fofonov A.V., Shamanaev V.S., Shmargunov V.P. Samolet-laboratoriya AN-30 «Optik-E»: 20 let issledovanij okruzhayushchej sredy // Optika atmosf. i okeana. 2009. V. 22, N 10. P. 950–957.
  44. Gerken T., Wei D., Chase R.J., Fuentes J.D., Schumacher C., Machado L.A.T., Andreoli R.V., Chamecki M., Ferreira de Souza R.A., Freire L.S., Jardine A.B., Manzi A.O., Nascimento dos Santos R.M., von Randow C., Costa P.S., Stoy P.C., Tota J., Trowbridge A.M. Downward transport of ozone rich air and implications for atmospheric chemistry in the Amazon rainforest // Atmos. Environ. 2016. V. 124. P. 64–76.

Back