Vol. 31, issue 10, article # 2

Sinitsa L.N., Serdyukov V.I., Polovtseva E.R., Bykov A.D. LED-based Fourier-transform spectroscopy: absorption spectrum of HD16O in the region of 0.6 mm. // Optika Atmosfery i Okeana. 2018. V. 31. No. 10. P. 787–790 [in Russian].
Copy the reference to clipboard

A high resolution vibrational-rotational absorption spectrum of НD16О molecule has been studied in the visible region from 16600 to 17400 cm-1 by LED-based Fourier-transform spectroscopy. The spectrum was recorded with the Fourier spectrometer IFS-125M with a resolution of 0.09 cm-1. A high-brightness light-emitting diode ЗНР was used as a source of radiation. For the measurements we used a White-type multi-pass cell with an optical path length of 2880 cm. The spectral line parameters (line centers and intensities) were determined. The line list contains more than 300 transitions to vibrational states (005) and (104). The obtained results are compared with the calculated and experimental data of other authors.


Fourier-Transform spectroscopy, absorption spectrum of HD16O molecule, spectral line centers and intensities


    1.    Joussaume S., Sadourny R., Jouzel J. A general circulation model of water isotope cycles in the atmosphere // Nature (Gr. Brit.). 1984. V. 311, N 5981. P. 24–29.
   2. Schneider M., Hase F., Blumenstock T. Ground-based remote sensing of HDO/H2O ratio profiles: Introduction and validation of an innovative retrieval approach // Atmos. Chem. Phys. 2006. V. 6, N 12. P. 4705–4722.
   3. Bykov A.D., Sinitsa L.N., Starikov V.I. Eksperimental'nye i teoreticheskie metody v spektroskopii molekul vodyanogo para. Novosibirsk: Izd-vo SO RAN, 1999. 376 p.
   4. Bykov A.D., Kapitanov V.A., Naumenko O.V., Petrova T.M., Serdyukov V.I., Sinitsa L.N. The laser spectroscopy of highly excited vibrational states of HD16O // J. Mol. Spectrosc. 1992. V. 153, N 1–2. P. 197–207.
   5. Bertseva E., Naumenko O., Campargue A. The 5VOH overtone transition of HDO // J. Mol. Spectrosc. 2000. V. 203, N 1. P. 28–36.
   6. Campargue A., Bertseva E., Naumenko O. The absorption spectrum of HDO in the 16 300–16 670 and 18 000–18 350 cm-1 spectral regions // J. Mol. Spectrosc. 2000. V. 204, N 1. P. 94–105.
   7. Bach M., Fally S., Coheur P., Carleer M., Jenouvrier A., Vandaele A. Line parameters of HDO from high-resolution Fourier transform spectroscopy in the 11500–23000 cm-1 spectral region // J. Mol. Spectrosc. 2005. V. 232, N 2. P. 341–350.
   8. Voronin B.A., Naumenko O.V., Carleer M., Coheur P.-F., Fally S., Jenouvrier A., Tolchenov R.N., Vandaele A.C., Tennyson J. HDO absorption spectrum above 11500 cm-1: Assignment and dynamics // J. Mol. Spectrosc. 2007. V. 244. P. 87–101.
   9. Partridge H., Schwenke D.W. The determination of an accurate isotope dependent potential energy surface for water from extensive ab initio calculations and experimental data // J. Chem. Phys. 1997. V. 106, N 11. P. 4618–4639.
10. Schwenke D.W., Partridge H. Convergence testing of the analytic representation of an ab initio dipole moment function for water: Improved fitting yields improved intensities // J. Chem. Phys. 2000. V. 113, N 16. P. 6592–6597.
11. Serdyukov V.I., Sinitsa L.N., Vasil'chenko S.S. Highly sensitive Fourier transform spectroscopy with LED sources // J. Mol. Spectrosc. 2013. V. 290. P. 13–17.
12. Serdyukov V.I. New possibilities of highly sensitive molecular absorption spectra in the visible region of the spectrum // Atmos. Ocean. Opt. 2013. V. 26. P. 817–821.
13. Serdyukov V.I., Sinitsa L.N., Vasil’chenko S.S., Voronin B.A. High-sensitive Fourier-transform spectroscopy with short-base multipass absorption cells // Atmos. and Ocean. Opt. 2013. V. 26. P. 329–36.
14. URL: http://spectra.iao.ru (last access: 20.05.2018).
15. Yukhnevich G.V. Infrakrasnaya spektroskopiya vody. M.: Nauka, 1973. 209 p.
16. Tennyson J., Bernath P.F., Brown L.R., Campargue A., Császár A.G., Daumont L., Gamache R.R., Hodges J.T., Naumenko O.V., Polyansky O.L., Rothman L.S., Vandaele A.C., Zobov N.F., Al Derzi A.R., Fábri C., Fazliev A.Z., Furtenbacher T., Gordon I.E., Lodi L., Mizus I.I. IUPAC critical evaluation of the rotational–vibrational spectra of water vapor. Part III. Energy levels and transition wavenumbers for H216O // J. Quant. Spectrosc. Radiat. Transfer. 2013. V. 117. P. 29–58.
17. Kruglova T.V., Shcherbakov A.P. Avtomaticheskij poisk linij v molekulyarnykh spektrakh na osnove metodov neparametricheskoj statistiki. Regulyarizatsiya v otsenke parametrov spektral'nykh linij // Optika i spektroskopiya. 2011. V. 111, N 3. P. 383.
18. Lavrentieva N., Voronin B., Naumenko O., Bykov A., Fedorova A. Linelist of HD16O for study of atmosphere of terrestrial planets (Earth, Venus and Mars) // Icarus. 2014. V. 236. P. 38.
19. URL: http://wadis.saga.iao.ru (last access: 20.05.2018).