Vol. 28, issue 04, article # 1

Lavrentieva N. N., Dudaryonok A. S., Buldyreva J. V. Calculation of methylcyanide line broadening coefficients: self- and nitrogen-broadening. // Optika Atmosfery i Okeana. 2015. V. 28. No. 04. P. 285-290 [in Russian].
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Abstract:

Calculated self- and nitrogen-broadening coefficients of methylcyanide lines are presented. The calculations are performed at the room temperature (Т = 296 K) for ~ 1 400 lines, rotational quantum numbers vary in ranges 0 ≤ J ≤ 70; 0 ≤ K ≤10. The temperature exponents for every value of broadening in the case of the Earth and Titan atmospheres temperature ranges are calculated. The calculations are made by a semi-empirical method, which is a modification of impact theory, based on the use of measured values of line contour parameters. A good agreement is obtained with experimental data.

Keywords:

line-broadening, symmetric top, methylcyanide, line-contour, intermolecular interactions

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