Vol. 21, issue 09, article # 2

Starikov V.I. Calculation of the self-broadening coefficients of D2O absorption lines using the exact trajectory model. // Atmospheric and oceanic optics. 2008. V. 21. No. 09. P. 652-655.
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Abstract:

The self-broadening coefficients γ and pressure-induced frequency shift coefficients δ of the ν2, ν1 + ν2, 3ν2, and ν2 + ν3 vibrational-rotational bands of D2O molecule were calculated in the framework of the semiclassical approach, taking into account the exact trajectory model. The influence of the accidental resonances on values of γ and δ was investigated. The computed coefficients γ were fitted to an empirical expression.

Keywords:

self-broadening, D2O, stochastic resonances, analytical relation

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