Vol. 11, issue 01, article # 4

Sulakshina O. N., Borkov Yu. G. Derivatives of the dipole moment functions for isotopic species of the ozone molecule. // Atmospheric and oceanic optics. 1998. V. 11. No. 01. P. 18-22.    PDF
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Abstract:

A method for studying the isotope substitution effect based on an analysis of transformations of intramolecular coordinates that allows one to establish isotopic relations between molecular constants and spectroscopic parameters has been applied to the ozone molecule. The lower-order derivatives of the dipole moment functions with respect to the normal coordinates have been calculated for all isotopic species of the ozone molecule with the help of the data on the main isotope of ozone.