Vol. 9, issue 01, article # 14

Starikov V.I. Some peculiarities of effective Hamiltonian reduction for the interacting states in nonrigid H2O-type molecules. // Atmospheric and oceanic optics. 1996. V. 9. No. 01. P. 67–73.
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Abstract:

Some peculiarities of effective Hamiltonian reduction have been considered for the interacting vibrational states of nonrigid H2O-type molecules. It has been demonstrated that reduced forms of operators describing interaction between vibrational states (n) and (m) depend on the degree of excitation of vibrational quantum number ν2 associated with the high-amplitude oscillations.

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