Vol. 6, issue 06, article # 10

Zvereva N. A., Ippolitov I. I., Terpugova A. F. Laser-induced photofragmentation of molecules. A theoretical study of photochemistry and photophysics of organic molecules. // Atmospheric and oceanic optics. 1993. V. 6. No. 06. P. 699-703.    PDF
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Abstract:

New method for detection nonfluorescing molecules and molecules whose spectra overlap is discussed. The approach proposed in this paper is based on different dependences of the photodissociation rates on the wavelength of the exciting radiation for different molecules. In order to vеrify the proposed technique a theoretical study and estimation of the radical OH dissociation from a number of aliphatic alcohols as well as of the formyl radical COH from some aldehydes have been carried out.