Vol. 4, issue 06, article # 15

Zuev V. V., Petrova A. I. The effect of change of the velocity of the absorbing molecule on the accuracy of calculation of the half-widths and the shifts of the spectral lines based on the RATCF model. // Atmospheric and oceanic optics. 1991. V. 4. No. 06. P. 485-486.    PDF
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Abstract:

It has been shown using the molecules CO2 and CO as an example that if the change of the velocity (Δν=Ιν(i)-v(f)Ι) of the absorbing molecule in the quantum transition from the state i to the state f is at a level of 0,2 • 104 cm/s, then the results of calculation of the parameters of the half–width γ and the shift δ of the spectral lines based on the refined Anderson–Tsao–Curnutte–Frost (RATCF) model in terms of the velocity v(i, f) averaged over the states i and f lie within the limits of the experimental error obtained for the functional dependence f(v(i), v(f)).