Vol. 27, issue 06, article # 5

Voronetskaya N.G., Pevneva G.S., Golovko A.K., Kozlov A.S., Arshinov M.Yu., Belan B.D., Simonenkov D.V., Tolmachev G.N. Hydrocarbon composition of tropospheric aerosol in the south of West Siberia. // Optika Atmosfery i Okeana. 2014. V. 27. No. 06. P. 496–505 [in Russian].
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Abstract:

In this paper, some methodical aspects of airborne sampling of aerosol particles, extraction of organic matter form aerosol samples, and identification of organic compounds are discussed. The investigation of a possible influence of aviation fuel and lubricants (kerosene, oil, hydraulic fluid) on measurement data has been performed. The composition of organic particulate matter sampled during winter and spring 2013 in the 500–7000 m atmospheric layer over Karakan Pine Forest located near the shore of Novosibirsk reservoir has been analyzed. The following compounds were identified: n-alkanes, cyclanes, and alkylarenes. For the first time in the particulate matter sampled in West Siberia the saturated cyclic and alkyl aromatic hydrocarbons have been revealed.

Keywords:

atmospheric aerosol, composition, hydrocarbons, n-alkanes, cyclanes, alkylnaphthalenes, alkylphenanthrenes

References:

1. Zaveri R.A., Shaw W.J., Cziczo D.J., Schmid B., Ferrare R.A., Alexander M.L., Alexandrov M., Alvarez R.J., Arnott W.P., Atkinson D.B., Baidar S., Banta R.M., Barnard J.C., Beranek J., Berg L.K., Brechtel F., Brewer W.A., Cahill J.F., Cairns B., Cappa C.D., Chand D., China S., Comstock J.M., Dubey M.K., Easter R.C., Erickson M.H., Fast J.D., Floerchinger C., Flowers B.A., Fortner E., Gaffney J.S., Gilles M.K., Gorkowski K., Gustafson W.I., Gyawali M., Hair J., Hardesty R.M., Harworth J.W., Herndon S., Hiranuma N., Hostetler C., Hubbe J.M., Jayne J.T., Jeong H., Jobson B.T., Kassianov E.I., Kleinman L.I., Kluzek C., Knighton B., Kolesar K.R., Kuang C., Kubátová A., Langford A.O., Laskin A., Laulainen N., Marchbanks R.D., Mazzoleni C., Mei F., Moffet R.C., Nelson D., Obland M.D., Oetjen H., Onasch T.B., Ortega I., Ottaviani M., Pekour M., Prather K.A., Radney J.G., Rogers R.R., Sandberg S.P., Sedlacek A., Senff C.J., Senum G., Setyan A., Shilling J.E., Shrivastava M., Song C., Springston S.R., Subramanian R., Suski K., Tomlinson J., Volkamer R., Wallace H.W., Wang J., Weickmann A.M., Worsnop D.R., Yu X.-Y., Zelenyuk A., Zhang Q. Overview of the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) // Atmos. Chem. Phys. 2012. V. 12, N 16. P. 7647–7687.
2. Fuks N.A. Mehanika ajerozolej. M.: AN SSSR, 1955. 351 p.
3. Kondrat'ev K.Ja. Ajerozol' kak klimatoobrazujushhij komponent atmosfery. 2. Prjamoe i kosvennoe vozdejstvie na klimat // Optika atmosf. i okeana. 2002. V. 15, N 4. P. 301–320.
4. Bialek J., Dall’Osto M., Monahan C., Beddows D., O’Dowd C. On the contribution of organics to the North East Atlantic aerosol number concentration // Environ. Res. Lett. 2012. V. 7. 044013. 7 p.
5. Elsasser M., Crippa M., Orasche J., DeCarlo P.F., Oster M., Pitz M., Cyrys J., Gustafson T.L., Pettersson J.B.C., Schnelle-Kreis J., Prevot A.S.H., Zimmermann R. Organic molecular markers and signature from wood combustion particles in winter ambient aerosols: aerosol mass spectrometer (AMS) and high time-resolved GC-MS measurements in Augsburg, Germany // Atmos. Chem. Phys. 2012. V. 12, N 14. P. 6113–6128.
6. Ge X., Wexler A.S., Clegg S.L. Atmospheric amines – Part 1. A review // Atmos. Environ. 2011. V. 45, N 3. Р. 524–545.
7. Wang Z., Wang T., Guo J., Gao R., Xue L., Zhang J., Zhou Y., Zhou X., Zhang Q., Wang W. Formation of secondary organic carbon and cloud impact on carbonaceous aerosols at Mount Tai, North China // Atmos. Environ. 2012. V. 46, N 1. P. 516–527.
8. Shakya K.M., Place P.F., Jr., Griffin R.J., Talbot R.W. Carbonaceous content and water-soluble organic functionality of atmospheric aerosols at a semi-rural New England location // J. Geophys. Res. 2012. V. 117. D03301. DOI: 10.1029/2011JD016113.
9. Kim K.H., Sekiguchi K., Kudo S., Kinoshita M., Sakamoto K. Carbonaceous and ionic components in ultrafine and fine particles at four sampling sites in the vicinity of roadway intersection // Atmos. Environ. 2013. V. 74. P. 83–92.
10. Pio C., Cerqueira M., Harrison R.M., Nunes T., Mirante F., Alves C., Oliveira C., de la Campa A.S., Artiñano B., Matos M. OC/EC ratio observations in Europe: Re-thinking the approach for apportionment between primary and secondary organic carbon // Atmos. Environ. 2011. V. 45, N 34. P. 6121–6132.
11. Heringa M.F., DeCarlo P.F., Chirico R., Tritscher T., Clairotte M., Mohr C., Crippa M., Slowik J.G., Pfaffenberger L., Dommen J., Weingartner E., Prevot A.S.H., Baltensperger U. A new method to discriminate secondary organic aerosols from different sources using high-resolution aerosol mass spectra // Atmos. Chem. Phys. 2012. V. 12, N 4. P. 2189–2203.
12. Perrone M.R., Piazzalunga A., Prato M., Carofalo I. Composition of fine and coarse particles in a coastal site of the central Mediterranean: Carbonaceous species contributions // Atmos. Environ. 2011. V. 45, N 39. P. 7470–7477.
13. Zhang X., Liu J., Parker E.T., Hayes P.L., Jimenez J.L., de Gouw J.A., Flynn J.H., Grossberg N., Lefer B.L., Weber R.J. On the gas-particle partitioning of soluble organic aerosol in two urban atmospheres with contrasting emissions: 1. Bulk water-soluble organic carbon // J. Geophys. Res. 2012. V. 117. D00V16. DOI: 10.1029/ 2012JD017908.
14. Zhang X., Liu Z., Hecobian A., Zheng M., Frank N.H., Edgerton E.S., Weber R.J. Spatial and seasonal variations of fine particle water-soluble organic carbon (WSOC) over the southeastern United States: implications for secondary organic aerosol formation // Atmos. Chem. Phys. 2012. V. 12, N 14. P. 6593–6607.
15. Ziemba L.D., Griffi R.J., Whitlow S., Talbot R.W. Characterization of water-soluble organic aerosol in coastal New England: Implications of variations in size distribution // Atmos. Environ. 2011. V. 45, N 39. P. 7310–7329.
16. Pöhlker Ch., Wiedemann K.T., Sinha B., Shiraiwa M., Gunthe S.S., Smith M., Su H., Artaxo P., Chen Q., Cheng Y., Elbert W., Gilles M.K., Kilcoyne A.L.D., Moffet R.C., Weigand M., Martin S.T., Pöschl U., Andreae M.O. Biogenic Potassium Salt Particles as Seeds for Secondary Organic Aerosol in the Amazon // Science. 2012. V. 337, N 6098. P. 1075–1078.
17. McNeill V.F., Grannas A.M., Abbatt J.P.D., Ammann M., Ariya P., Bartels-Rausch T., Domine F., Donaldson D.J., Guzman M.I., Heger D., Kahan T.F., Klan P., Masclin S., Toubin C., Voisin D. Organics in environmental ices: sources, chemistry, and impacts // Atmos. Chem. Phys. 2012. V. 12, N 20. P. 9653–9678.
18. Burrows S.M., Hoose C., Pöschl U., Lawrence M.G. Ice nuclei in marine air: biogenic particles or dust? // Atmos. Chem. Phys. 2013. V. 13, N 1. P. 245–267.
19. Ervens B., Wang Y., Eagar J., Leaitch W.R., Macdonald A.M., Valsaraj K.T., Herckes P. Dissolved organic carbon (DOC) and select aldehydes in cloud and fog water: the role of the aqueous phase in impacting trace gas budgets // Atmos. Chem. Phys. 2013. V. 13, N 10. P. 5117–5135.
20. Lee D.Y., Wexler A.S. Atmospheric amines – Part III: Photochemistry and toxicity // Atmos. Environ. 2013. V. 71. P. 95–103.
21. Park J.-H., Goldstein A.H., Timkovsky J., Fares S., Weber R., Karlik J., Holzinger R. Active Atmosphere–Ecosystem Exchange of the Vast Majority of Detected Volatile Organic Compounds // Science. 2013. V. 341, N 6146. P. 643–647.
22. Doyle G.J. Self-nucleation in the sulfuric acid-water system // J. Chem. Phys. 1961. N 35. P. 795–799.
23. Kulmala M., Vehkamäki H., Petäjä T., Dal Maso M., Lauri A., Kerminen V.M., Birmili W., McMurry P.H. Formation and growth rates of ultrafine atmospheric particles: a review of observations // J. Aerosol Sci. 2004. V. 35, N 2. P. 143–176.
24. Kroll J.H., Seinfeld J.H. Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere // Atmos. Environ. 2008. V. 42, N 16. P. 3593–3624.
25. Kiendler-Scharr A., Wildt J., Dal Maso M., Hohaus T., Kleist E., Mentel T.F., Tillmann R., Uerlings R., Schurr U., Wahner A. New particle formation in forests inhibited by isoprene emissions // Nature (Gr. Brit.). 2009. V. 461, N 7262. P. 381–383.
26. Pierce J.R., Riipinen I., Kulmala M., Ehn M., Petäjä T., Junninen H., Worsnop D.R., Donahue N.M. Quantification of the volatility of secondary organic compounds in ultrafine particles during nucleation events // Atmos. Chem. Phys. 2011. V. 11, N 17. P. 9019–9036.
27. Ortega I.K., Suni T., Boy M., Gronholm T., Manninen H.E., Nieminen T., Ehn M., Junninen H., Hakola H., Hellen H., Valmari T., Arvela H., Zegelin S., Hughes D., Kitchen M., Cleugh H., Worsnop D.R., Kulmala M., Kerminen V.-M. New insights into nocturnal nucleation // Atmos. Chem. Phys. 2012. V. 12, N 9. P. 4297–4312.
28. Liu S., Day D.A., Shields J.E., Russell L.M. Ozone-driven daytime formation of secondary organic aerosol containing carboxylic acid groups and alkane groups // Atmos. Chem. Phys. 2011. V. 11, N 16. P. 8321–8341.
29. Wang H.L., Huang D., Zhang X., Zhao Y., Chen Z.M. Understanding the aqueous phase ozonolysis of isoprene: distinct product distribution and mechanism from the gas phase reaction // Atmos. Chem. Phys. 2012. V. 12, N 15. P. 7187–7198.
30. Barnum T.J., Medeiros N., Hinrichs R.Z. Condensed-phase versus gas-phase ozonolysis of catechol: A combined experimental and theoretical study // Atmos. Environ. 2012. V. 55, N 1. P. 98–106.
31. Kiendler-Scharr A., Andres S., Bachner M., Behnke K., Broch S., Hofzumahaus A., Holland F., Kleist E., Mentel T.F., Rubach F., Springer M., Steitz B., Tillmann R., Wahner A., Schnitzler J.-P., Wildt J. Isoprene in poplar emissions: effects on new particle formation and OH concentrations // Atmos. Chem. Phys. 2012. V. 12, N 2. P. 1021–1030.
32. Epstein S.A., Nizkorodov S.A. A comparison of the chemical sinks of atmospheric organics in the gas and aqueous phase // Atmos. Chem. Phys. 2012. V. 12, N 17. P. 8205–8222.
33. Eddingsaas N.C., Loza C.L., Yee L.D., Chan M., Schilling K.A., Chhabra P.S., Seinfeld J.H., Wennberg P.O. a-pinene photooxidation under controlled chemical conditions. Part 2: SOA yield and composition in low- and high-NOx environments // Atmos. Chem. Phys. 2012. V. 12, N 16. P. 7413–7427.
34. Rollins A.W., Browne E.C., Min K.-E., Pusede S.E., Wooldridge P.J., Gentner D.R., Goldstein A.H., Liu S., Day D.A., Russell L.M., Cohen R.C. Evidence for NOx Control over Nighttime SOA Formation // Science. 2012. V. 337, N 6099. P. 1210–1212.
35. Liu Ch., Chu B., Liu Y., Ma Q., Ma J., He H., Li J., Hao J. Effect of mineral dust on secondary organic aerosol yield and aerosol size in a-pinene/NOx photo-oxidation // Atmos. Environ. 2013. V. 77. P. 781–789.
36. Riccobono F., Rondo L., Sipila M., Barmet P., Curtius J., Dommen J., Ehn M., Ehrhart S., Kulmala M., Kurten A., Mikkila J., Paasonen P., Petäjä T., Weingartner E., Baltensperger U. Contribution of sulfuric acid and oxidized organic compounds to particle formation and growth // Atmos. Chem. Phys. 2012. V. 12, N 20. P. 9427–9439.
37. Gensch I., Laumer W., Stein O., Kammer B., Hohaus T., Saathoff H., Wegener R., Wahner A., Kiendler-Scharr A. Temperature dependence of the kinetic isotope effect in b-pinene ozonolysis // J. Geophys. Res. 2011. V. 116. D20301. DOI: 10.1029/2011JD016084.
38. Day M.C., Pandis S.N. Predicted changes in summertime organic aerosol concentrations due to increased temperatures // Atmos. Environ. 2011. V. 45, N 36. P. 6546–6556.
39. Chu B., Hao J., Takekawa H., Li J., Wang K., Jiang J. The remarkable effect of FeSO4 seed aerosols on secondary organic aerosol formation from photooxidation of a-pinene/NOx and toluene/NOx // Atmos. Environ. 2012. V. 55, N 1. P. 26–34.
40. Isidorov V.A. Organicheskaja himija atmosfery. L.: Himija, 1985. 264 p.
41. Welz O., Savee J.D., Osborn D.L., Vasu S.S., Percival C.J., Shallcross D.E., Taatjes C.A. Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2 // Science. 2012. V. 335, N 6065. P. 204–207.
42. Su Y.-T., Huang Y.-H., Witek H.A., Lee Y.-P. Infrared Absorption Spectrum of the Simplest Criegee Intermediate CH2OO // Science. 2013. V. 340, N 6129. P. 174–176.
43. Taatjes C.A., Welz O., Eskola A.J., Savee J.D., Scheer A.M., Shallcross D.E., Rotavera B., Lee E.P.F., Dyke J.M., Mok D.K.W., Osborn D.L., Percival C.J. Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO // Science. 2013. V. 340, N 6129. P. 177–180.
44. Cappa C.D., Che D.L., Kessler S.H. et al. Variations in organic aerosol optical and hygroscopic properties upon heterogeneous OH oxidation // J. Geophys. Res. 2011. V. 116. D15203. DOI: 10.1029/2010JD015435.
45. Zhong M., Jang M. Light absorption coefficient measurement of SOA using a UV-Visible spectrometer connected with an integrating sphere // Atmos. Environ. 2011. V. 45, N 25. P. 4263–4271.
46. Isidorov V.A. Organicheskaja himija atmosfery. SPb.: Himija, 2001. 352 p.
47. Ravindra K., Sokhi R., Van Grieken R. Atmospheric polycyclic aromatic hydrocarbons: Source attribution, emission factors and regulation // Atmos. Environ. 2008. V. 42, N 13. P. 2895–2921.
48. Fowler D., Pilegaard K., Sutton M.A., Ambus P., Raivonen M., Duyzer J., Simpson D., Fagerli H., Fuzzi S., Schjoerring J.K., Granier C., Neftel A., Isaksen I.S.A., Lajo P., Maione M., Monks P.S., Burkhardt J., Daemmgen U., Neirynck J., Personne E., Wichink-Kruit R., Butterbach-Bahl K., Flechard C., Tuovinen J.P., Coyle M., Gerosa G., Loubet B., Altimir N., Gruenhage L., Ammann C., Cieslik S., Paoletti E., Mikkelsen T.N., Ro-Poulsen H., Cellier P., Cape J.N., Horvath L., Loreto F., Niinemets U., Palmer P.I., Rinne J., Misztal P., Nemitz E., Nilsson D., Pryor S., Gallagher M.W., Vesala T., Skiba U., Bruggemann N., Zechmeister-Boltenstern S., Williams J., O’Dowd C., Facchini M.C., de Leeuw G., Flossman A., Chaumerliac N., Erisman J.W. Atmospheric composition change: Ecosystems–Atmosphere interactions // Atmos. Environ. 2009. V. 43, N 33. P. 5193–5267.
49. Anohin G.G., Antohin P.N., Arshinov M.Ju., Barsuk V.E., Belan B.D., Belan S.B., Davydov D.K., Ivlev G.A., Kozlov A.V., Kozlov V.S., Morozov M.V., Panchenko M.V., Penner I.Je., Pestunov D.A., Sikov G.P., Simonenkov D.V., Sinicyn D.S., Tolmachev G.N., Filippov D.V., Fofonov A.V., Chernov D.G., Shamanaev V.S., Shmargunov V.P. Samolet-laboratorija Tu-134 «Optik» // Optika atmosf. i okeana. 2011. V. 24, N 9. P. 805–816.
50. Mazurek M.A., Cass G.R., Simoneit B.R.T. Interpretation of high-resolution gas chromatography and high-resolution gas chromatography/mass spectrometry data acquired from atmospheric organic aerosol samples // Aerosol Sci. Technol. 1989. V. 10, N 2. P. 408–420.
51. Rogge W.F., Hildemann L.M., Mazurek M.A., Cass G.R., Simoneit B.R.T. Sources of fine organic aerosol. 4. Particulate abrasion products from leaf surfaces of urban plants // Environ. Sci. Technol. 1993. V. 27, N 13. P. 2700–2711.
52. Rogge W.F., Hildemann L.M., Mazurek M.A., Cass G.R., Simoneit B.R.T. Sources of fine organic aerosol. 5. Natural gas home appliances // Environ. Sci. Technol. 1993. V. 27, N 13. P. 2736–2744.
53. Rogge W.F., Hildemann L.M., Mazurek M.A., Cass G.R., Simoneit B.R.T. Sources of fine organic aerosol. 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks // Environ. Sci. Technol. 1993. V. 27, N 4. P. 636–651.
54. Hayes P.L., Ortega A.M., Cubison M.J., Froyd K.D., Zhao Y., Cliff S.S., Hu W.W., Toohey D.W., Flynn J.H., Lefer B.L., Grossberg N., Alvarez S., Rappenglück B., Taylor J.W., Allan J.D., Holloway J.S., Gilman J.B., Kuster W.C., de Gouw J.A., Massoli P., Zhang X., Liu J., Weber R.J., Corrigan A.L., Russell L.M., Isaacman G., Worton D.R., Kreisberg N.M., Goldstein A.H., Thalman R., Waxman E.M., Volkamer R., Lin Y.H., Surratt J.D., Kleindienst T.E., Offenberg J.H., Dusanter S., Griffith S., Stevens P.S., Brioude J., Angevine W.M., Jimenez J.L. Organic aerosol composition and sources in Pasadena, California, during the 2010 CalNex campaign // J. Geophys. Res. 2013. V. 118, N 16. P. 9233–9257. DOI: 10.1002/jgrd.50530.
55. Crippa M., Canonaco F., Slowik J.G., Haddad I.El., DeCarlo P.F., Mohr C., Heringa M.F., Chirico R., Marchand N., Temime-Roussel B., Abidi E., Poulain L., Wiedensohler A., Baltensperger U., Prevot A.S.H. Primary and secondary organic aerosol origin by combined gas-particle phase source apportionment // Atmos. Chem. Phys. 2013. V. 13, N 16. P. 8411–8426.
56. Yee L.D., Craven J.S., Loza C.L., Schilling K.A., Ng N.L., Canagaratna M.R., Ziemann P.J., Flagan R.C., Seinfeld J.H. Effect of chemical structure on secondary organic aerosol formation from C12 alkanes // Atmos. Chem. Phys. 2013. V. 13, N 21. P. 11121–11140.

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